Spectroscopic and Mechanistic Studies of Dinuclear Metallohydrolases and Their Biomimetic Complexes
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Beschreibung
Introduction.- Experimental.- Understanding the Overall Structure of GpdQ and Metal Binding.- Structural and Mechanistic Studies of Zn(II) Complexes as Phosphoesterase Models.- Mechanistic Studies of Cd(II) Complexes as Phosphoesterase and Metallo-beta-lactamase Models.- Spectroscopic and Mechanistic Studies of Co(II) Phosphoesterase and Metallo-beta-lactamase Biomimetics.- Asymmetric Zn(II) Complexes as Structural and Functional Models for GpdQ.- Immobilization of GpdQ and Related Models for Bioremedial Applications.- Conclusion and Outlook.
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